GEOMORPHOLOGY OF STEEPLAND HEADWATERS: THE TRANSITION FROM HILLSLOPES TO CHANNELS1

Headwater streams comprise 60 to 80 percent of the cumulative length of river networks. In hilly to mountainous terrain, they reflect a mix of hillslope and channel processes because of their close proximity to sediment source areas. Their morphology is an assemblage of residual soils, landslide deposits, wood, boulders, thin patches of poorly sorted alluvium, and stretches of bedrock. Longitudinal profiles of these channels are strongly influenced by steps created by sediment deposits, large wood, and boulders. Due to the combination of small drainage area, stepped shallow gradient, large roughness elements, and cohesive sediments, headwater streams typically transport little sediment or coarse wood debris by fluvial processes. Consequently, headwaters act as sediment reservoirs for periods spanning decades to centuries. The accumulated sediment and wood may be episodically evacuated by debris flows, debris floods, or gully erosion and transported to larger channels. In mountain environments, these processes deliver significant amounts of materials that form riverine habitats in larger channels. In managed steepland forests, accelerated rates of landslides and debris flows resulting from the harvest of headwater forests have the potential to seriously impact the morphology of headwater streams and downstream resources.     

Biodegradability of algal-derived organic matter in a large artificial lake by using stable isotope tracers

In order to understand the biodegradability of algal-derived organic matter, biodegradation experiments were conducted with ¹³C and ¹⁵N-labeled natural phytoplankton and periphytic algal populations in experimental conditions for 60 days. Qualitative changes in the dissolved organic matter were also determined using parallel factor analysis and the stable carbon isotopic composition of the hydrophobic dissolved organic matter through the experimental period. Although algal-derived organic matter is considered to be easily biodegradable, the initial amounts of total organic carbon newly produced by phytoplankton and periphytic algae remained approximately 16 and 44 % after 60 days, respectively, and about 22 and 43 % of newly produced particulate nitrogen remained. Further, the dissolved organic carbon derived from both algal populations increased significantly after 60 days. Although the dissolved organic matter gradually became refractory, the contributions of the algal-derived organic matter to the dissolved organic matter and hydrophobic dissolved organic matter increased. Our laboratory experimental results suggest that algal-derived organic matter produced by phytoplankton and periphytic algae could contribute significantly to the non-biodegradable organic matter through microbial transformations.     

Experimental investigation of a 250-kW turbine organic Rankine cycle system for low-grade waste heat recovery

An organic Rankine cycle (ORC) is generally used for converting low-grade heat into electricity. In this study, an extensive literature survey was conducted to identify current research gaps on experimental ORC systems. Specifically, there is limited experimental data and limited details on thermal and expander efficiencies of ORC systems. In order to address these gaps, the objective of this study included developing a turbine ORC with a power output exceeding 50 kW and thermal efficiency exceeding 8% for a heat source temperature < 120°C. The experimental results indicated that the system achieved a net power output of 242.5 kW and a thermal efficiency of 8.3% (the highest value for a turbine ORC system for the heat source temperature below 120°C). Thus, the study addressed the gaps identified in the research area of ORCs.     

Recharge and Flow in the Medicine Lake Volcano–Fall River Springs Groundwater Basin,California

Isotopic measurements of the 34 m³/s discharge from the Fall River Springs of northern California indicate recharge from 50 km upgradient in high elevation regions of Medicine Lake Volcano. Age determinations suggest less than 20-year travel time. Data demonstrate Klamath Basin further north cannot be a recharge source. Mass balance calculations support that annual precipitation on the volcano supplies observed spring discharge, requiring 50%–75% recharge rates. Radiocarbon and δ¹³C of dissolved inorganic carbon indicate 30%–40% is derived from magmatic CO₂. Measured excess ³He is also consistent with the presence of magmatic gas derived from the Quaternary Age Medicine Lake Volcano.     

Cancer risk from gaseous carbonyl compounds in indoor environment generated from household coal combustion in Xuanwei,China

Airborne carbonyls were characterized from emitted indoor coal combustion. Samples were collected in Xuanwei (Yunnan Province), a region in China with a high rate of lung cancer. Eleven of 19 types of samples (58%) demonstrated formaldehyde concentrations higher than the World Health Organization exposure limit (a 30-min average of 100 μg m^?3). Different positive significant correlations between glyoxal/methylglyoxal and formaldehyde/acetaldehyde concentrations were observed, suggesting possible different characteristics in emissions between two pairs of carbonyl compounds. A sample in the highest inhalation risk shows 29.2 times higher risk than the lowest sample, suggesting different coal sampling locations could contribute to the variation of inhalation risk. Inhabitants in Xuanwei also tend to spend more time cooking and more days per year indoors than the national average. The calculated cancer risk ranged from 2.2–63 × 10^?5, which shows 13 types of samples at high-risk level. Cumulative effect in combination with different carbonyls could have contributed to the additive actual inhalation cancer risk. There is a need to explicitly address the health effects of environmentally relevant doses, considering life-long exposure in indoor dwellings.     

Urinary levels of phthalate metabolites and associations with demographic characteristics in Korean adults

The objective of this study is to assess human exposure to phthalates and its associations with demographic characteristics of the subjects in the Korean National Human Biomonitoring Survey. The subjects aged between 18 and 69 were selected through nationwide stratified sampling. A total of 1874 urine samples were collected and stored at ?20 °C until measurement for ten selected metabolites of phthalates (MnBP, MiBP, MBzP, MCHP, MnOP, MEHP, MEOHP, MEHHP, MiNP, and MiDP) using high-performance liquid chromatography-tandem mass spectrometry (LC-MS/MS). The difference in the level of urinary phthalate metabolites by the characteristics of the subjects was tested for statistical significance using SAS Surveyreg procedure. The coefficients and standard errors from multiple linear regressions were exponentiated to estimate the adjusted proportional change (APC) and 95% CIs compared with a referent level. The proportion of data above LOQ was less than 20% for MCHP, MnOP, MiNP, and MiDP. Geometric means of creatinine-adjusted concentrations (unit: μg/g creatinine) of six other phthalate metabolites among Korean adults were 41.7 (95% CI 39.6–43.9) for MnBP, 17.1 (95% CI 16.1–18.1) for MiBP, 15.7 (95% CI 14.4–17.1) for MBzP, 8.65 (95% CI 8.10–9.22) for MEHP, 17.5 (95% CI 16.8–18.3) for MEOHP, and 38.1 (95% CI 36.2–40.2) for MEHHP. Urinary level of phthalates tended to be higher among subjects with older age, females, and those with vigorous daily physical activity and tended to be lower among drinkers and those with higher income. Our results suggest that the level of phthalate exposure is significant among Korean adults and thus warrants further studies to identify major source and route of exposure to phthalates.     

Stable isotope on the evaluation of water quality in the presence of WWTPs in rivers

Environmental Science and Pollution Research - We investigated the distribution of nitrogen compounds in Han River as well as two tributaries of Tancheon and Jungrangcheon. Particularly, we...     

Inhibition of residual <Emphasis Type="Italic">n</Emphasis>-hexane in anaerobic digestion of lipid-extracted microalgal wastes and microbial community shift

Converting lipid-extracted microalgal wastes to methane (CH₄) via anaerobic digestion (AD) has the potential to make microalgae-based biodiesel platform more sustainable. However, it is apparent that remaining n-hexane (C₆H₁₄) from lipid extraction could inhibit metabolic pathway of methanogens. To test an inhibitory influence of residual n-hexane, this study conducted a series of batch AD by mixing lipid-extracted Chlorella vulgaris with a wide range of n-hexane concentration (～10 g chemical oxygen demand (COD)/L). Experimental results show that the inhibition of n-hexane on CH₄ yield was negligible up to 2 g COD/L and inhibition to methanogenesis became significant when it was higher than 4 g COD/L based on quantitative mass balance. Inhibition threshold was about 4 g COD/L of n-hexane. Analytical result of microbial community profile revealed that dominance of alkane-degrading sulfate-reducing bacteria (SRB) and syntrophic bacteria increased, while that of methanogens sharply dropped as n-hexane concentration increased. These findings offer a useful guideline of threshold n-hexane concentration and microbial community shift for the AD of lipid-extracted microalgal wastes.     

Quality control for coal combustion products in South Korea through assessed pozzolanic-activity index with long-term property tests

In South Korea, nine million tons of fly ash (FA) are annually produced and approximately 70 % is reutilized for industrial demand. For the prompt reuse and insufficient reclamation site, quality control of FA which is main productive construction material from coal ash is very important. Assessed Pozzolanic-activity Index (API) test which needs only 2 days for evaluation of pozzolanic reaction is currently considered as an alternative of activity index measurement. This paper aims for an applicability of API test for prompt quality control and investigation of domestic FA properties. For the work, FAs from two different power plant types are prepared, and quality tests are carried out based on Korean Standards (KS) methods and API method. Lots of test results are compared with those from API and K-value test for FA with age of 7 days–1 year. From the test results for FA aged 1 year, API results are evaluated to be closely related with those from activity index and K-value, and the correlations are improved with increasing ages regardless of plant types. The applicability of API test is verified and the reduced period of FA quality evaluation can accelerate prompt use and the related process of FA.